姓名:张林星
职称职务:特任副研究员,硕士生导师
研究方向:理论与计算化学
地址:williamhill官网化学化工学院D217
E-mail:linxing.zhang@hubu.edu.cn
学习及工作经历:
2024.07-至今,williamhill官网化学化工学院,专任教师
2021.09-2023.09,帝国理工学院,博士后,合作导师:Mark Crimmin教授
2015.09-2020.08,北京大学,博士,导师:张欣豪副教授、吴云东教授
2011.09-2015.06,williamhill官网,本科
研究方向简介:
长期从事理论与计算化学研究,致力于各类有机和无机化学反应的理论研究,主要研究方向包括:1.过渡金属催化的反应机理研究;2.主族金属参与及催化的反应机理研究;3.数据驱动的配体导向催化反应的机理研究。
承担科研项目:
1.国家自然科学基金青年项目(22403028),主持,在研
2.中国博士后科学基金面上项目(2022M722217),主持,已结题
代表性论文:
1.L.Zhang,#P.Chen,#X.-P.Zhang, C.Yang, T.-Y.Sun*, X.Zhang*, Y.-D.Wu*, Palladium/Norbornene-Cocatalyzed Ortho-Amination of Aryl Iodides: A Systematic Elucidation of the Mechanisms and Roles of Cs2CO3 Base via Computational and Mass Spectrometric Approaches.ACS Catal.,2023,13, 8588-8599.
2.L.Zhang, S.Kaukver, J.McMullen, A.J. P. White, M.R. Crimmin*,Catalytic C–H Alumination of Thiophenes: DFT Predictions and Experimental Verification.Organometallics,2023,42, 1711-1716.
3.F.Rekhroukh,#L.Zhang,#R.Y. Kong, A.J. P. White, M.R. Crimmin*, Stereoselective Insertion of Cyclopropenes into Mg–Mg Bonds.Chem.Commun.,2022,58, 8282-8285.
4.L.Zhang,#K.An,#Y.Wang,#Y.-D.Wu, X.Zhang*, Z.-X.Yu*, W.He*, A Combined Computational and Experimental Study of Rh-Catalyzed C–H Silylation with Silacyclobutanes: Insights Leading to a More Efficient Catalyst System.J.Am.Chem.Soc.,2021, 143,3571-3582.
5.L.Chen,#L.Zhang,#Y.Shao, G.Xu, X.Zhang*, S.Tang, J.Sun*, Rhodium-Catalyzed C=N Bond Formation through a Rebound Hydrolysis Mechanism and Application in β-Lactam Synthesis.Org.Lett.,2019,21, 4124-4127.
6.X.Meng,#B.Yang,#L.Zhang,#G.Pan, X.Zhang*, Z.Shao*, Rh(II)/Brønsted Acid Catalyzed General and Highly Diastereo- and Enantioselective Propargylation of in Situ Generated Oxonium Ylides and C-Alkynyl N-Boc N, O-Acetals: Synthesis of Polyfunctional Propargylamines.Org.Lett.,2019,21, 1292-1296.
7.L.Zhang, X.Zhang, Y.-D.Wu*, Y.Xie, J.M. Fukuto, H.F Schaefer*, The Reaction of Alkyl Hydropersulfides (RSSH, R = CH3 and tBu) with H2S in the Gas Phase and in Aqueous Solution.Phys.Chem.Chem.Phys.,2019,21, 537-545.(Cover Paper)